Here's a convenient link to the forum: Question & Answer Collection.
Upon loading up the game you'll be asked to pick your language, for the purpose of using my question and answer guide select 'English (US)'. After this menu you'll be asked to create your profile after pressing 
.
We'll be concentrating on trying to earn the trophy for perfecting a 5-Round game so we'll be playing that game type first.
From the main menu select 'Play Trivial Pursuit Live!' and then 'Party Play' then select '5-Round' and most importantly 'Single Controller' so that we can control all 4 players with a single controller, both saving you buying more AND meaning we can have a pop up between each question (for passing the controller to the next player) which helps see the question you're answering.
Now its time to add your 4 players, press and select your main profile (Should be named as your PSNID) and choose your player character. Now repeat this step only this time you'll need to make new game profiles for each of the 3 remaining players. Once all 4 players are in the game press 
to begin the game.
Just in case here's a video showing setup for 5-Round.
https://www.trueachievements.com/gameclip.aspx?clipid=167596...
Remember that you can pause the game with at any time and I also suggest making use of the PS4's game DVR and screenshot functionality to help with looking up answers.
There are 5 rounds which consist of:
- Quickstarter - 5 questions, 4 from one category and the last from another. You need to get all 5 correct
- Grab Bag - 4 questions each with 8 answers out of a possible 16. You need to pick all 8 for each question so the other players cannot pick any correct ones
- Switchagories - 4 questions, different category each time. Again you need to answer all 4 correct
- Close Call - 5 questions. All 5 answers are correct but you must get the top answer
- Rapid Fire - You should only need 2 wedges at this final round so you'll only see 2 different categories. You'll be given a question with 2 answers to choose from.
Note: Switchagories and Quickstarter can swap places as can Grab Bag and Close Call.
Providing you have answered every question correctly you should unlock the following from your first game
Don’t fret too much if you don’t get a perfect game on you're first try as it will all help with other trophies anyway, like wins, questions answered, titles earned and wedges won. If you did earn 'Pop Goes Perfection' its up to you to either switch to 3-Round games with you and one other player or carry on with 5-Round games. What I would suggest to do is carry on doing 4 more games of 5 Rounds as it'll help answer more questions.
Switching to 3-Round though is simple, choose 3-Round and at the player select screen add yourself and one other player as before but instead of adding more press 
to remove the AI players, then press to play and carry on as before using the forum: Question & Answer Collection.
Just in case here's a video showing setup for 3-Round with 2 human players only.
https://www.trueachievements.com/gameclip.aspx?clipid=167597...
After winning your 5th game you should have earned 30 wedges (5x6=30) to unlock:
Now all that is left is to keep playing to win you remaining games for your total of 25 wins.
Whilst doing this you should hopefully also answer 50 questions correctly (Each Grab Bag question can yield 8 correct answers) in each of the 6 categories as well as earning the 30 titles detailed in the 'Titles' page along the way.
Congratulations on your completion.
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