This is my first time ever writing a trophy guide so please give me any tips that can help you guys understand it better and of course anything you'd like to add, be my guest!
This trophy is fairly simple even if you're starting on Super-Hero mode. But it may take a few tries to understand the Hunters' moves.
You want to alternate between swinging and Web-Rush. Chase after the Hunters then start to Web-Rush and Web-Shoot rapidly (R1 while spamming the O button), until you are prompted to attack the robot (R1/Web-Rush). Once Spidey leaps off of the robot, swing once then begin to Web-Rush and Web-Shoot again. Rinse and repeat until you get prompted to 'Deactivate Hunter', which of course is with the R1 button. You should repeat this process until both bots are down.
Now I should also note that every now and again the Hunters will emit a very large electrical AOE attack which should be dodged immediately. As you may be caught a little inside it while Web-Rushing, just turn in any direction you find easiest and rush out of there. The chase will then continue where you can put the first method back into play!