This trophy is for wearing 5 different suits in spider man.
The 1st 3 suits you will have access to is your damaged classic suit, your repaired classic suit, and the advanced suit.
If you pre ordered the game, you will already have the spider punk suit, the iron spider suit, and the velocity suit.
With the 1st 3 suits, and the 3 pre order suits, you will get this trophy by trying them all on.
If you did not pre order the game and do not have the 3 extra suits, the old just have to unlock suits through natural progression.
Unlocking the extra suits require some combination of:
base tokens (awarded after clearing Fisks Bases)
crime tokens (awarded after stopping crimes)
research tokens (awarded after completing Mini games related to otto octavius's research)
backpack tokens (awarded for every backpack collectible you find throughout the city),
and landmark tokens (awarded after every landmark you photograph)
You must at least progress a little through a story to unlock the ability to attack bases, do research, and find out about collecting backpacks and taking photos of landmarks.