To earn the trophy that's called "I Read Every Move," you will need to not get hit a single time during the fight and win it.
There are a couple of ways to go about getting this trophy.
If you want to win this legitimately, go to Fight, then Versus. Start a solo match, then adjust the difficulty level to 2 from the COM LEVEL option. By doing this, your opponent will not be very aggressive against you, allowing you to crush them easily. Also, make sure to put this for one round so that you can expedite the process faster for the trophy.
Another alternative is to have two controllers and just do a versus fight. The second controller remains idle while you just beat the heck out of them for both rounds. I also suggest the same advice for making this only one round so that you don't have to waste extra effort to go through two rounds.
Finally, there's also the boosting method. By that, I mean you can find someone online, whether it's a friend or a complete stranger, that's willing to stand there and let you get the trophy as long as you do the same for them in return.
Personally, I recommend the first two options. It's a lot faster that way!
Have fun and good luck!