Here is the full list of all 50 Pro Evolution Soccer 2019 (EU) trophies - there are 40 bronze, 6 silver, 3 gold and 1 platinum.
Perfect Collection
Created a Squad with a Team Strength of 2,300 or more in myClub
Won a total of 100 matches
Performed a total of 100 assists
Defeated 5 Match Level: Super Star opponents
Got match data in VERSUS Mode
Played a total of 50 matches
Got match data against COM in VERSUS Mode
Trained a player to Lv.35 in myClub
Pulled off a win by scoring in stoppage time
Played Full Exhibition Match
Won a derby match
Awarded Acclaim for playing 10 ranked matches in myClub
Scored a total of 100 goals
Obtained a BLACK rarity player with a myClub Agent
Had the ball 65% or more of the time and won the match
Won after coming back from 2 goals down
Netted a free kick from 25 m or more
Played a Random Selection Match to the final whistle
Won a Casual Match in Online CO-OP
Awarded a special CO-OP Playing Style in Online CO-OP
Obtained a GOLD or BLACK rarity player with a myClub Scout
Won a Clan Match in Online CO-OP
Kicked off while taking part in a Team Play Lobby
Awarded for being promoted to a higher division in [Online Divisions]
Defeated an opponent ★2 or stronger in Team Strength
Awarded for winning your first [Online Divisions] match
Awarded for winning your first RANKED MATCH game in myClub
A defender scored a goal
Scored in open play from 30 m or more (excluding Set Pieces)
Saved a penalty kick (no penalty shootouts)
Performed a trick to get past a player and score
Awarded for being named World Player of the Year in [Become a Legend]
Awarded for being picked for the Team of the Season in [Become a Legend]
Awarded for winning the League Title in [Become a Legend]
Scored 5 goals from chip shots
Awarded for making an appearance in [Become a Legend]
Scored 3 goals using a Set Piece Strategy
Awarded for winning the League Title in any of the Top Leagues featured in [Master League]
Registered a player to My Favorite Players in [Master League]
Won the International Champions Cup
Awarded for earning a win in [Master League]
Shutout the opposition
Awarded for obtaining Silver in all [Expert] level Skills Training
Awarded for obtaining Silver in all [Advanced] level Skills Training
Awarded for obtaining Silver in all [Intermediate] level Skills Training
Awarded for obtaining Silver in all [Basic] level Skills Training
A substitute scored
Scored 3 goals with the same player in a match
Scored a goal on a counterattack